The First Law of Thermodynamics
 

The First Law of Thermodynamics problem 38


  • The specific latent heat of vaporisation of water at atmospheric pressure of is . A mass of of liquid water at . is provided with the thermal energy needed to vaporise all of the water at atmospheric pressure.


    • Calculate the thermal energy supplied to the water.


    • The mass of of water is . Assume that water vapour can be considered to behave as an ideal gas. Show that the volume of water vapour produced is .


    • Assume that the initial volume of the liquid water is negligible compared with the volume of water vapour produced. Determine the magnitude of the work done by the water in expanding against the atmosphere when it vaporises.


    • Use your answers in (a)(i) and (a)(iii) to determine the increase in internal energy of the water when it vaporises at . Explain your reasoning.


  • Use the first law of thermodynamics to suggest, with a reason, how the specific latent heat of vaporisation of water at a pressure greater than atmospheric pressure compares with its value at atmospheric pressure.


 

main author and content editor: Ebenezer Famadewa