
The kinetic theory of gases is based on some simplifying assumptions. The molecules of the gas are assumed to behave as hard elastic identical spheres. State the assumption about ideal gas molecules based on
the nature of their movement,
their volume.
A cube of volume
contains
molecules of an ideal gas. Each molecule has a component
of velocity normal to one side S of the cube, as shown in the figure below.
The pressure
of the gas due to the component
of velocity is given by the expression

where
is the mass of a molecule.
Explain how the expression leads to the relation

where
is the mean square speed of the molecules.
The molecules of an ideal gas have a root-mean-square (r.m.s.) speed of
at a temperature of
. Calculate the r.m.s. speed of the molecules at a temperature of
.